4:21:49.5
Assume that X minutes after 4.00 PM minute hand exactly aligns with and hour hand.
For every minute, minute hand travels 6 degrees.
Hence, for X minutes it will travel 6 * X degrees.
For every minute, hour hand travels 1/2 degrees.
Hence, for X minutes it will travel X/2 degrees.
At 4.00 PM, the angle between minute hand and hour hand is 120 degrees. Also, after X minutes, minute hand and hour hand are exactly aligned. So the angle with respect to 12 i.e. Vertical Plane will be same. Therefore,
6 * X = 120 + X/2
12 * X = 240 + X
11 * X = 240
X = 21.8182
X = 21 minutes 49.5 seconds
Hence, at 4:21:49.5 minute hand is exactly aligned with the hour hand.
